Whoa! I didn't know this could be done, but obviously it can!
Deborah Jin's group at NIST has produced another amazing experimental result. This time they did what is essentially an analogous experiment of photoemission spectroscopy done on electronic system, but this time done on ultracold atomic gas!
Abstract: Ultracold atomic gases provide model systems in which to study many-body quantum physics. Recent experiments using Fermi gases have demonstrated a phase transition to a superfluid state with strong interparticle interactions. This system provides a realization of the 'BCS–BEC crossover connecting the physics of Bardeen–Cooper–Schrieffer (BCS) superconductivity with that of Bose–Einstein condensates (BECs). Although many aspects of this system have been investigated, it has not yet been possible to measure the single-particle excitation spectrum (a fundamental property directly predicted by many-body theories). Here we use photoemission spectroscopy to directly probe the elementary excitations and energy dispersion in a strongly interacting Fermi gas of 40K atoms. In the experiments, a radio-frequency photon ejects an atom from the strongly interacting system by means of a spin-flip transition to a weakly interacting state. We measure the occupied density of single-particle states at the cusp of the BCS–BEC crossover and on the BEC side of the crossover, and compare these results to that for a nearly ideal Fermi gas. We show that, near the critical temperature, the single-particle spectral function is dramatically altered in a way that is consistent with a large pairing gap. Our results probe the many-body physics in a way that could be compared to data for the high-transition-temperature superconductors. As in photoemission spectroscopy for electronic materials, our measurement technique for ultracold atomic gases directly probes low-energy excitations and thus can reveal excitation gaps and/or pseudogaps. Furthermore, this technique can provide an analogue of angle-resolved photoemission spectroscopy for probing anisotropic systems, such as atoms in optical lattice potentials.
The "work function" for the system has been replaced with the Zeeman energy splitting, since the system obviously doesn't really have a surface energy.
 J.T. Stewart et al., Nature v.454, p.744 (2008).